ANGREN SERIY TABIIY KAOLIN GILLARIDAN PAST HARORATLI GIDROTERMIK USULDA NAX SEOLITINING SINTEZI

Xakberdiyev Shuxrat Mahramovich Jizzax politexnika instituti Kimyo kafedrasi mudiri Kimyo fanlari bo`yicha falsafa doktori (PhD), dotsent

Authors

  • Pardaev Otabek Toʻxtamishovich , Abdurahmonov Eldor Baratovich , Normamatov Abdujabor Mamatraimovich Author

Keywords:

NaX seolitlari, kaolinit gillari, gidroksisodalit, gidrotermal transformatsiya.

Abstract

NaX seolitlari eng qimmatli sintetik seolitlardan biri boʻlib, sanoatda ion almashinadigan materiallar, katalizatorlar va adsorbentlar sifatida keng qoʻllaniladi. Shuning uchun uni arzon va ekologik toza xom ashyolardan sintez qilishning tejamkorroq usulini tanlash kerak. Yaxshi kristalllikka ega kaolindan NaX seolitini olish. Bu uchun Angren konnidan uchta tanlangan joydan namunalar (Ik, Ok va Ka) olingan. Tanlangan kaolinit gillari (Ik, Ok va Ka) dastlab toza kukunlarni (75 mkm) oʻlchov birligi olish uchun ehtiyotkorlik bilan boyitilgan. Qayta ishlangan kaolinit gil kukunlari keyin mufel pechida qizdirildi 800 °C haroratda 3,5 soat davomida, 10 °C / mint isitish tezligi bilan. Kaolinit gillarining tegishli metakaolinlarga aylanishi. Keyin hosil boʻlgan metakaolinlar NaOH eritmalari bilan har xil darajada reaksiyaga kirishdi past harorat yordamida mos ravishda 3,0 va 4,0 M konsentratsiyalari NaX seolit kukunlarini ishlab chiqarish uchun gidrotermal transformatsiya. Olingan seolitlar skanerlash

References

G. Mousa, J.- Ch. Buhl, Synthesis and characterization of zeolite A by hydrothermal transformation of natural Jordanian kaolin, J. of the Assoc. of Arab Univ. for Basic and Appl. Sci. 15 (2014) 35 – 42.

D.W. Breck, Zeolites Molecular Sieves, Structure, Chemistry and Use. New York, John Wiley & Sons, 4 (1974) 771-780.

A.T. Chiang, K.J. Chao, Membranes and films of zeolite and zeolite like Materials, J. of Physics and Chemistry of Solids 62 (2001) 1899-1910.

S.M. Abegunde, K.S. Idowu, O.M. Adejuwon, T. Adeyemi-Adejolu, A review on the influence of chemical modification on the performance of adsorbents, Resources, Environment and Sustainability, 1(2020) 100001.

B.K. Marcus, W.E. Cormier, Going green with zeolites, Chemical Eng. Progress, 95(1999) 47-53.

E.M. Henry, C.E. Ikenna, I.L. Ganiyu, Zeolite synthesis, characterization and application areas: A Review. Int. Res. J. Environmental Sci. 6(2017) 45-59.

A.Y. Atta, O.A. Ajayi, S.S. Adefila, Synthesis of Faujasite zeolites from Kankara kaolin clay, J. App. Sci. Res. 3 (2007) 1017-1021.

Georgiev, D., Bogdanov, B., Angelova, K., Markovska, I., Hristov, Y., Synthetic zeolite – structure, classification, current trends in zeolite synthesis review. Int. Sci. conf., Stara Zagora, Bulgaria, (2009) 4 – 5.

S. Chandrasekhar, P.N. Pramada, Investigation on the synthesis of zeolite NaX from Kerala Kaolin, Journal of Porous Mater. 6 (1999) 283-297.

D.W. Breck, Synthetic zeolite: properties and applications, Lefond, S. J ed., Industrial Minerals and Rocks, New York, American Institute of Mining, Metallurgy and Petroleum Engineering, Inc. 3(7) (1975)1243- 1274.

R.M. Barrer, Zeolites and clay minerals as sorbents and molecular sieves, Academic Press, London. 1978.

A.Y. Atta, B.Y. Jibril, B.O. Aderemi, S.S. Adefila, Preparation of analcime from local kaolin and rice husk ash, Applied Clay Sci. 61 (2012) 8-13.

M. Alkan, C. Hopa, Z. Yilmaz, H. Güler, The effect of alkali concentration and solid/liquid ratio on the hydrothermal synthesis of zeolite NaX from natural kaolinite, Microporous and Mesoporous Mater. 86(1-3) (2005) 176-184.

H. Zhao, Y. Deng, J. Harsh, M. Flury, J. Boyle, Alteration of kaolinite to canrinite and sodalite by simulated Hanford waste and its impact on cesium retention. Calys Clay Miner. 52 (1) (2004) 1–13.

J.C. Covarrubias, R. Garcia, R. Arriagada, J. Yanez, T. Garland, Cr(III) exchange on zeolites obtained from kaolin and natural mordenite, Microporous Mesoporous Mater. 88 (2006) 220–231.

J. Mon, Y. Deng, M. Flury, J. Harsh, Cesium incorporation and diffusion in cancrinite, sodalite, zeolite, and allophane, Microporous Mesoporous Mater. 86 (2005) 277–286.

V. Sanhueza, U. Kelm, R. Cid, Synthesis of molecular sieves from Chilean kaolins: Synthesis of NaX type zeolite, J. Chem. Technol. Biotechnol. 74 (1999) 358–363.

L.M. Marcelo, I.P. Diego, R.C. Nadia, Fernandes.Machado, Sibele, B.C. Pergher, Synthesis of mordenite using kaolin as Si and Al source, Appl. Clay Sci. 41 (2007) 99–104.

J.B. Adeoye, J.A. Omoleye, M.E. Ojewumi, R. Babalola, Synthesis of zeolite Y from kaolin using novel method of dealumination, Inter. J. of Appl. Eng. Res. 12 (5) (2017) 755-760.

A.R. Carlos, D.W. Craig, M.C. Oscar, Crystallization of low silica Na-A and Na-X zeolites from transformation of kaolin and obsidian by alkaline fusion, Ingeniería y Competitividad 14 (2) (2012) 125 – 137.

N.J. Saikia, D.J. Bharali, P. Sengupta, D. Bordoloi, R.L. Goswamee, P.C. Saikia, P.C. Borthakur, Characterization, beneficiation and utilization of a kaolinite clay from Assam, India, Appl. Clay Sci. 24 (2003) 93– 103.

L. Vaculíková, E. Plevová, S. Vallová, I. Koutník, Characterization and differentiation of kaolinites from selected Czech deposits using infrared spectroscopy and differential thermal analysis, Acta Geodyn. Geomater. 8 (161) (2011) 59–67.

D. Makia, E. Georges, O. Jason, Fourier transform infrared spectroscopy and thermal analyses of kaolinitic clays from South Africa and Cameroon, Acta Geodyn. Geomater. 13 (2016) 149–158.

G. Zahra, Y. Habibollah, Preparation and characterization of nanozeolite NaX from rice husk at room temperature without organic additives, J. of Nanomaterials, 2011.

E.M. Flaningen, H.A. Khatami, H.A. Szymanski, Infrared structural study of zeolite frameworks, Molecular Sieve Zeolites 16 (1971) 201 – 229.

K. Byrappa, B.V. Suresh Kumar, Characterization of zeolites by infrared spectroscopy, Asian J. of Chem. 19 (6) (2007) 4933 – 4935.

E.F Olasehinde and S.M. Abegunde, Preparation and characterization of a new adsorbent from Raphia taedigera seed, Res. Eng. Struct. Mater., 2020; 6(2): 167-182.

S. Markovic, V. Dondur, R. Dimitrijevic, FTIR spectroscopy of framework aluminosil

Published

2024-09-10

How to Cite

Pardaev Otabek Toʻxtamishovich , Abdurahmonov Eldor Baratovich , Normamatov Abdujabor Mamatraimovich. (2024). ANGREN SERIY TABIIY KAOLIN GILLARIDAN PAST HARORATLI GIDROTERMIK USULDA NAX SEOLITINING SINTEZI: Xakberdiyev Shuxrat Mahramovich Jizzax politexnika instituti Kimyo kafedrasi mudiri Kimyo fanlari bo`yicha falsafa doktori (PhD), dotsent. IQRO INDEXING, 11(02), 134-145. https://worldlyjournals.com/index.php/IFX/article/view/5243